Words similar to thiolates
Example sentences for: thiolates
How can you use “thiolates” in a sentence? Here are some example sentences to help you improve your vocabulary:
Recent progress in this field points to a common chemistry in the reaction of H 2 O 2 with thiolates through the initial formation of sulfenic acid.
The pKa of the thiolates clearly plays an important role, as thiolates are more reactive than their protonated counterparts.
As mentioned above, proteins—in particular, the thiols of cysteines—are the major targets of H 2 O 2 . The reaction of cysteinyl thiolates with H 2 O 2 can lead to the formation of different modifications, such as sulfenic acid (–SOH), sulfinic acid (–SO 2 H), and sulfonic acid (–SO3H), as well as disulfide bond formation (–S–S–) and glutathione conjugation (–S–GSH) (Jacob et al.
Furthermore, the reactivity of a thiol depends upon its pKa, as thiolates are orders of magnitude more nucleophilic than thiols [ 54].