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Example sentences for: hyperfine

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The 51V hyperfine splitting spectra from molecules with V=O bond perpendicular to the magnetic field (A⊥) are much smaller and not shown here [ 21 ] . The intensity of -5/2 || peak is used as direct measurement of the amount of bound VO 2+, since this peak is the most intense peak in the EPR spectrum that contains contribution only from A || but not A⊥ [ 21 26 ] . In this study, the intensities of each bound VO 2+-EPR feature were normalized to 1 mg of protein.
Vanadyl has been used to estimate the types of groups that serve as metal-ligands in F 1 -ATPase and other enzymes [ 16 18 19 21 ] because the g and A tensors of the 51V hyperfine couplings are approximately a linear combination of tensors from each type of group that contributes an equatorial ligand [ 24 27 ] . By studying the EPR spectra of bound VO 2+in the presence of different nucleotides, we show that the interaction of soluble CD39 with ATP is different from that with ADP.
This spectrum shows 51V hyperfine splitting and the center of the parallel transitions from molecules with the V=O bond oriented along the magnetic field (A || , g || ) which are strong enough to tell the nature of VO 2+equatorial ligands [ 22 ] . Of the eight transitions that result from the parallel oriented molecules, the -7/2 || , -5/2 || , +3/2 || , +5/2 || , and +7/2 || transitions (shown in the figures from left to right, respectively) do not overlap with perpendicular transitions.