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Example sentences for: hyperfine

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Vanadyl has been used to estimate the types of groups that serve as metal-ligands in F 1 -ATPase and other enzymes [ 16 18 19 21 ] because the g and A tensors of the 51V hyperfine couplings are approximately a linear combination of tensors from each type of group that contributes an equatorial ligand [ 24 27 ] . By studying the EPR spectra of bound VO 2+in the presence of different nucleotides, we show that the interaction of soluble CD39 with ATP is different from that with ADP.
The 51V hyperfine splitting spectra from molecules with V=O bond perpendicular to the magnetic field (A⊥) are much smaller and not shown here [ 21 ] . The intensity of -5/2 || peak is used as direct measurement of the amount of bound VO 2+, since this peak is the most intense peak in the EPR spectrum that contains contribution only from A || but not A⊥ [ 21 26 ] . In this study, the intensities of each bound VO 2+-EPR feature were normalized to 1 mg of protein.
This spectrum shows 51V hyperfine splitting and the center of the parallel transitions from molecules with the V=O bond oriented along the magnetic field (A || , g || ) which are strong enough to tell the nature of VO 2+equatorial ligands [ 22 ] . Of the eight transitions that result from the parallel oriented molecules, the -7/2 || , -5/2 || , +3/2 || , +5/2 || , and +7/2 || transitions (shown in the figures from left to right, respectively) do not overlap with perpendicular transitions.